Intramolecular Energy Relaxation and Statistical Rate Theory
نویسندگان
چکیده
منابع مشابه
Vibrational energy relaxation rate constants from linear response theory
A new approach for the calculation of vibrational energy relaxation rate constants is introduced. The new approach is based on linear response theory, and is shown to have several distinct advantages over the standard Landau–Teller formula, which is based on the Bloch–Redfield theory, namely: ~1! weak system–bath coupling is not assumed; ~2! selectivity in choosing the vibrational energy relaxa...
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Intramolecular vibrational energy relaxation (IVR) in nitrous acid (HONO) is studied with the help of ultrafast two-color pump-probe spectroscopy. In a previous paper [V. Botan et al., J. Chem. Phys. 124, 234511 (2006)], it has been observed that trans-HONO cools through a cascade of overtones of one specific mode after pumping the OH stretch vibration. We had suggested that this cooling mode i...
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ژورنال
عنوان ژورنال: Progress of Theoretical Physics Supplement
سال: 2013
ISSN: 0375-9687
DOI: 10.1143/ptp.116.167